saint+ version 6.02 (Bruker Corporation)
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saint+ version 6.02
Saint+ Version 6.02, supplied by Bruker Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/saint+6%2E02/saint+version+6+02/pm40300448-122-15-19
Average 90 stars, based on 1 article reviews
Saint+ Version 6.02, supplied by Bruker Corporation, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
https://www.bioz.com/product/saint+6%2E02/saint+version+6+02/pm40300448-122-15-19
Average 90 stars, based on 1 article reviews
saint+ version 6.02 - by Bioz Stars,
2026-10
90/100 stars
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other:Article Title: Reversible Hydride Migration from C 5 Me 5 to Rh I Revealed by a Cooperative Bimetallic Approach Article Snippet: [5] Article Title: Synthesis of new heteroscorpionate iridium(I) and iridium(III) complexes. Article Snippet: Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content.. The journal’s standard Terms & Conditions and the Ethical guidelines still apply.. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. Article Title: Terphenyl complexes of molybdenum and tungsten with quadruple metal-metal bonds and bridging carboxylate ligands. Article Snippet: Monoand bis-terphenyl complexes of molybdenum and tungsten with general composition M2(Ar’)(O2CR)3 and M2(Ar’)2(O2CR)2, respectively (Ar’ = terphenyl ligand), that contain carboxylate groups bridging the quadruply bonded metal atoms, have been prepared and structurally characterized.. The new compounds stem from the reactions of the dimetal tetracarboxylates, M2(O2CR)4 (M = Mo, R = H, Me, CF3; M = W, R = CF3) with the lithium salts of the appropriate terphenyl groups (Ar’ = Ar2, Ar2, Ar2 and Ar2).. Substitution of one bidentate carboxylate by a monodentate terphenyl forms a M−C σ bond and creates a coordination unsaturation at the other metal atom. Article Title: Base-Promoted, Remote C–H Activation at a Cationic (η 5 -C 5 Me 5 )Ir(III) Center Involving Reversible C–C Bond Formation of Bound C 5 Me 5 Article Snippet: 2 Article Title: Diaminohexopyranosides as Ligands in Half-Sandwich Ruthenium(II), Rhodium(III), and Iridium(III) Complexes Article Snippet: The syntheses of methyl 2,3-diamino-4,6-Obenzylidene-2,3-dideoxy-α-D-hexopyranosides of glucose, mannose, gulose, and talose and methyl 2-amino-4,6-benzylidene2,3-dideoxy-3-tosylamido-α-D-glucopyranoside are exhaustively presented, as well as their application as ligands in halfsandwich ruthenium(II), rhodium(III), and iridium(III) complexes.. The complex formation occurs highly diastereoselectively, creating a stereogenic metal center.. The molecular structures of the ligands and their complexes were investigated by X-ray structure analysis, NMR spectroscopy, polarimetry, and DFT methods. Article Title: Family of Isomeric Cu II -Ln III (Ln = Gd, Tb, and Dy) Complexes Presenting Field-Induced Slow Relaxation of Magnetization Only for the Members Containing Gd III . Article Snippet: The strategic design and synthesis of two isomeric Cu complexes, [CuL] and [CuL], of asymmetrically dicondensed N2O3-donor Schiff-base ligands (where H2L A and H2L B are N-salicylidene-N′-3-methoxysalicylidenepropane-1,2-diamine and N-3-methoxysalicylidene-N′-salicylidenepropane-1,2-diamine, respectively) have been accomplished via a convenient Cu template method.. These two complexes have been used as metalloligands for the synthesis of three pairs of Cu−Ln isomeric complexes [CuL(μ-NO3)Ln(NO3)2(H2O)]· CH3CN (for complexes 1A−3A, L = L, and for complexes 1B−3B, L = L and Ln = Gd, Tb, and Dy, respectively), all of which have been characterized structurally.. In all six isomorphous and isostructural complexes, the decacoordinated Ln centers and pentacoordinated Cu centers possess sphenocorona and square-pyramidal geometries, respectively. Article Title: Two Keggin-Based Isostructural POMOF Hybrids: Synthesis, Crystal Structure, and Catalytic Properties. Article Snippet: In this work we synthesized two novel isostructural twin hybrids Comp1: [H(C10H10N2)Cu2][PMo12O40] & Comp2: [H(C10H10N2)Cu2][PW12O40], based on the Keggin ions (PMo12O40 −3 & PW12O40 −3), Cu(I) cation, and 4,4′-bipyridine, by in situ hydrothermal reduction of Cu, facilitated through extensive standardizations of synthetic pH conditions.. Both compounds crystallized in monoclinic P21/c space group with similar lattice parameters and crystal structures.. The structural similarity prompted us to explore comparative catalytic properties of the hybrids, to understand the relative role of the POM species in the activity. Article Title: Crystal Engineering in Supramolecular Polyoxometalate Hybrids through pH Controlled in Situ Ligand Hydrolysis. Article Snippet: A family of five different three-dimensional polyoxometalate (POM) based supramolecular hybrids were synthesized by a hydrothermal route under different pH using a hydrolyzable naphthalene diimide ligand.. The mechanism of crystallographic phase variation of the POM-amino pyridine hybrids under different pH was studied through controlled experiments where the final hydrolyzed products were analyzed through NMR and single crystal X-ray diffraction.. Different pH conditions led to variation in the extent of protonation and hydrolyzation of the ligand, yielding different phases. |